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Acid Rain

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What is Acid Rain?

Acid rain is a rain or any other form of precipitation that is unusually acidic, meaning that it possesses elevated levels of hydrogen ions (low pH). It can have harmful effects on plants, aquatic animals and infrastructure. Acid rain is caused by emissions of sulphur dioxide and nitrogen oxide, which react with the water molecules in the atmosphere to produce acids. Some governments have made efforts since the 1970s to reduce the release of sulphur dioxide and nitrogen oxide into the atmosphere with positive results. Nitrogen oxides can also be produced naturally by lightning strikes, and sulphur dioxide is produced by volcanic eruptions. Acid rain has been shown to have adverse impacts on forests, freshwaters and soils, killing insect and aquatic life-forms, causing paint to peel, corrosion of steel structures such as bridges, and weathering of stone buildings and statues as well as having impacts on human health.

 

Causes of Acid Rain:-

Natural Sources:- The major natural causal agent for acid rain is volcanic emissions. Volcanoes emit acid producing gases to create higher than normal amounts of acid rain or any other form of precipitation such as fog and snow to an extent of affecting vegetation cover and health of residents within the surrounding. Decaying vegetation, wildfires and biological processes within the environment also generate the acid rain forming gases. Dimethyl sulphide is a typical example of a major biological contributor to sulphur containing elements into the atmosphere. Lightning strikes also naturally produce nitric oxides that react with water molecules via electrical activity to produce nitric acid, thereby forming acid rain.

Man-made sources:- Human activities leading to chemical gas emissions such as sulphur and nitrogen are the primary contributors to acid rain. The activities include air pollution sources emitting sulphur and nitrogen gases like factories, power generations facilities, and automobiles. In particular, use of coal for electrical power generation is the biggest contributor to gaseous emissions leading to acid rain. Automobiles and factories also release high scores of gaseous emissions on daily basis into the air, especially in highly industrialized areas and urban regions with large numbers of car traffic. These gases react in the atmosphere with water, oxygen, and other chemicals to form various acidic compounds such as sulfuric acid, ammonium nitrate, and nitric acid. As a result, these areas experience exceedingly high amounts of acid rain.

The existing winds blow these acidic compounds over large areas across borders and they fall back to the ground in the form of acid rain or other forms of precipitation. Upon reaching the earth, it flows across the surface, absorbs into the soil and enters into lakes and rivers and finally gets mixed up with sea water.

 

Effects of Acid Rain:-

Effect on Aquatic Environment:- Acid rain either falls directly on aquatic bodies or gets run off the forests, roads and fields to flow into streams, rivers and lakes. Over a period of time, acids get accumulated in the water and lower the overall pH of the water body. The aquatic plants and animals need a particular pH level of about 4.8 to survive. If the pH level falls below that the conditions become hostile for the survival of aquatic life. Acid rain tendency of altering pH and aluminium concentrations greatly affects pH concentration levels in surface water, thereby affecting fish as well as other aquatic life-forms. At pH levels below 5, most fish eggs cannot hatch. Lower pHs can also kill adult fish. Acid rain runoff from catchment areas into rivers and lakes has also reduced biodiversity as rivers and lakes become more acidic. Species including fish, plant and insect types in some lakes, rivers and brooks have been reduced and some even completely eliminated owing to excess acid rain flowing into the waters.

Effect on Forests:- It makes trees vulnerable to disease, extreme weather, and insects by destroying their leaves, damaging the bark and arresting their growth. Forest damage due to acid rain is most evident in Eastern Europe – especially Germany, Poland and Switzerland.

Effect on Soil:- Acid rain highly impacts on soil chemistry and biology. It means, soil microbes and biological activity as well as soil chemical compositions such as soil pH are damaged or reversed due to the effects of acid rain. The soil needs to maintain an optimum pH level for the continuity of biological activity. When acid rains seep into the soil, it means higher soil pH, which damages or reverses soil biological and chemical activities. Hence, sensitive soil microorganisms that cannot adapt to changes in pH are killed. High soil acidity also denatures enzymes for the soil microbes. On the same breadth, hydrogen ions of acid rain leach away vital minerals and nutrients such as calcium and magnesium.

Vegetation Cover and Plantations:- The damaging effects of acid rain on soil and high levels of dry depositions have endlessly damaged high altitude forests and vegetation cover since they are mostly encircled by acidic fogs and clouds. Besides, the widespread effects of acid rain on ecological harmony have led to stunted growth and even death of some forests and vegetation cover.

Effect on Architecture and Buildings:- Acid rain on buildings, especially those constructed with limestone, react with the minerals and corrode them away. This leaves the building weak and susceptible to decay. Modern buildings, cars, airplanes, steel bridges and pipes are all affected by acid rain. Irreplaceable damage can be caused to the old heritage buildings.

Effect on Public Health:- When in atmosphere, sulphur dioxide and nitrogen oxide gases and their particulate matter derivatives like sulphates and nitrates, degrades visibility and can cause accidents, leading to injuries and deaths. Human health is not directly affected by acid rain because acid rain water is too dilute to cause serious health problems. However, the dry depositions also known as gaseous particulates in the air which in this case are nitrogen oxides and sulphur dioxide can cause serious health problems when in haled? Intensified levels of acid depositions in dry form in the air can cause lung and heart problems such as bronchitis and asthma.

Other Effects:- Acid rain leads to weathering of buildings, corrosion of metals, and peeling of paints on surfaces. Buildings and structures made of marble and limestone are the ones especially damaged by acid rain due to the reactivity of the acids in the rain and the calcium compounds in the structures. The effects are commonly seen on statues, old grave stones, historic monuments, and damaged buildings. Acid rain also corrodes metals like steel, bronze, copper, and iron.

 

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Solutions to Acid Rain:-

Restoring Damaged Environments:- Use of limestone or lime, a process called liming, is a practice that people can do to repair the damage caused by acid rain to lakes, rivers and brooks. Adding lime into acidic surface waters balances the acidity. It’s a process that has extensively been used, for instance in Sweden, to keep the water pH at optimum. Even though, liming is an expensive method and has to be done repeatedly. Furthermore, it only offers a short-term solution at the expense of solving the broader challenges of SO2 and NOx emissions and risks to human health. Nevertheless, it helps to restore and allow the survival of aquatic life forms by improving chronically acidified surface waters.

Alternative Energy Sources:- Besides fossil fuels, there is a wide range of alternative energy sources that can generate electrical power. These include wind energy, geothermal energy, solar energy, hydropower, and nuclear power. Harnessing these energy sources can offer effective electrical power alternatives instead of using fossil fuels. Fuel cells, natural gas, and batteries can also substitute use of fossil fuel as cleaner energy sources. As of today, all energy sources have environmental and economic costs as well as benefits. The only solution is using sustainable energy that can protect the future.

Individual, National/State, and International Actions:- Millions of people directly and indirectly contribute to SO2 and NOx emissions. Mitigation of this challenge requires individuals to be more informed about energy conservation and ways of reducing emissions such as: turning off lights or electrical appliances when not using them; use public transport; use energy efficient electrical appliances; and use of hybrid vehicles or those with low NOx emissions.

 

 

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